Evaluation of coal bed methane potential of coal seams of Sawang Colliery,Jharkhand, India     

Anil M. Pophare  Vinod A. Mendhe  A. Varade 《Journal of Earth System Science》2008,117(2):121-132

The coal seams of Sawang Colliery, East Bokaro Coalfields are bituminous to sub-bituminous in nature and categorized as high gaseous seams (degree II to degree III level). These seams have the potential for coal bed methane (CBM) and their maturity increases with increasing depth, as a result of enhanced pressure-temperature conditions in the underground. The vitrinite maceral group composition of the investigated coal seams ranges from 62.50–83.15%, whereas the inertinite content varies from 14.93–36.81%. The liptinite content varies from 0.66% to 3.09%. The maximum micro-pores are confined within the vitrinite group of macerals. The coal seams exhibit vitrinite reflectance values (Ro% calculated) from 0.94% (sample CG-97) to 1.21% (sample CG-119). Proximate analyses of the investigated coal samples reveal that the moisture content (M%) ranges from 1.28% to 2.98%, whereas, volatile matter (VM%) content is placed in the range of 27.01% to 33.86%. The ash content (A%) ranges from 10.92% to 30.01%. Fixed carbon (FC%) content varies from 41.53% to 55.93%. Fuel ratio variation shows a restricted range from 1.53 to 1.97. All the coal samples were found to be strongly caking and forming coke buttons. The present study is based on the adsorption isotherm experiments carried out under controlled P-T conditions for determination of actual gas adsorption capacity of the coal seams. This analysis shows that the maximum methane gas adsorbed in the coal sample CG-81 is 17 m³/t (Std. daf), at maximum pressure of 5.92 MPa and experimental temperature of 30°C. The calculated Langmuir regression parameters P_L and V_L range from 2.49 to 3.75 MPa and 22.94 to 26.88 m³/t (Std. daf), respectively.  相似文献   

土壤酶对碘离子在土壤中吸附行为的影响   总被引：1，自引：0，他引：1  

吴世军  陈繁荣  程俊  杨永强  吕莹  康明亮 《地球化学》2008,37(1):37-44

以批式试验法研究了微生物、葡萄糖氧化酶、脲酶、纤维素酶及其催化底物葡萄糖、尿素和纤维素对Ⅰ-在土壤中吸附的影响,结果表明微生物能显著提高Ⅰ-吸附量,但葡萄糖氧化酶、脲酶、纤维素酶及葡萄糖、尿素和纤维素对Ⅰ-吸附并无促进作用.葡萄糖氧化酶及葡萄糖含量在小于100 mg/L时对Ⅰ-吸附无影响,1000 mg/L时与Ⅰ-呈竞争吸附;脲酶及尿素随浓度增大,对Ⅰ-吸附的抑制作用变得明显;1～1000 mg/L范围内,纤维素酶和纤维素对Ⅰ-吸附没有影响;但葡萄糖氧化酶和葡萄糖生成的中间产物可促进土壤对Ⅰ-的吸附.平衡液中溶解性有机碳(DOC)含量随时间增加而逐渐降低,有机质浓度越大,降低趋势越明显.  相似文献   

沸石强化过滤的中试及生产性试验研究   总被引：2，自引：0，他引：2  

丁磊  王萍 《矿物学报》2008,28(3)

对新型水处理材料沸石强化常规给水处理工艺进行了中试和生产性试验,并与石英砂滤料做了对比.中试结果表明粒径为0.80-1.20mm沸石对浊度、氨氮、有机物都表现出良好的去除效果,过滤时的水头损失、反冲洗强度明显小于石英砂,不仅能满足反冲洗要求,还可节省反冲洗水量,降低运行成本.在生产性试验条件下,沸石对浊度、氨氮、耗氧量的去除率分别为95%、83%和39%.因此,在当前水源水遭到污染的情况下,用沸石替代石英砂滤料可明显改善水质,在不增加处理构筑物的情况下,对给水处理工艺可起到强化作用  相似文献   

钛型吸附剂的表面特性     

谢式南  王俊鹤  周英兰  孙爱平 《中国海洋大学学报(自然科学版)》1990,(3)

用自装的BET容量法装置测定了几种粒状钛型吸附剂的比表面及其孔径分布。测定是在常温减压下进行的。结果表明:钛型吸附剂在加铀海水中的吸铀量与样品的比表面及孔径分布有一定的内在联系。这种表面性质的研究对吸附剂的筛选有重要的指导意义。  相似文献   

石油污染物在海滩颗粒体系中吸附规律的研究   总被引：1，自引：0，他引：1  

夏文香  刘金雷  李金成  赵亮 《海洋通报》2006,25(5):17-21,83

以0#柴油为研究对象,探讨了石油污染物在海滩颗粒体系中的吸附规律,考察了吸附剂(沙粒)的粒径、海水盐度和温度三因素对吸附作用的影响,并对吸附机理进行了分析。结果表明,颗粒物对溶解油的吸附速率较快,其吸附量与沙粒粒径成反比,与盐度成正比,而温度的升高不利于吸附过程的进行。溶解油在颗粒物上的吸附为物理吸附,其吸附模式符合Henery等温吸附式。  相似文献   

固定化海藻吸附金属离子的影响因素   总被引：7，自引：0，他引：7  

王宪  邱海源  钱爱红  陈丽丹  郑盛华 《海洋学报》2006,28(1):62-66

研究了固定化海带吸附含铜、镉溶液过程的影响因素,结果表明,在pH为3.0~5.0时对Cu2+保持高的吸附率,在pH为4.0时对Cd2+的吸附率达到最大.随着Cu2+,Cd2+金属离子初始浓度的降低,吸附率有所降低.对Cd2+的吸附率均随着温度的升高而变大.随着吸附剂浓度的增大,对Cu2+,Cd2+的吸附率逐渐升高,与此相反,对Cu2+,Cd2+的吸附量则逐渐减小.粒径对Cu2+的吸附率影响较小,对Cd2+的吸附率有较明显的变化.  相似文献   

Study of Adsorption Isotherm Curves of Amino Acids on the Kaolinite     

刘效兰  张正斌 《海洋通报(英文版)》2002,4(1):52-60

This paper studies the adsorption isotherm curves of four amino acids (glyucine,aspartic acid,glutamic acid and lysine)and the effects of existences of different concentrations of Cu(Ⅱ) on them.Both the adsorption isotherm of the amino acids on the kaolinite and that when the copper ion Cu(Ⅱ） exists belong to the Langmuir type.The slopes of these adsorption isotherm increase with the increasing concentrations of Cu(Ⅱ） added.It can be explained in terms of formation of the type(Ⅰ） ternary surface complexes in these systems.The regular pattern of the effects of copper ion Cu(Ⅱ) on the adsorption isotherm of amino acids on the kaolinite is identical with that of its effects on the exchange and adsorption percentage E(%)-pH on the kaolinite in the same system.  相似文献   

砷酸根的液—固界面交换吸附研究——pH和Ca(Ⅱ)的影响     

赵卫红  张正斌 《中国海洋大学学报(自然科学版)》1997,(2)

研究ｐＨ和Ｃａ（Ⅱ）对砷酸根在海水与ＮａＣｌ介质中对水合氧化物和粘土矿物上交换吸附的影响：（１）在酸性条件下和海水及ＮａＣｌ介质中，砷酸根在针铁矿上的交换率Ｅ（％）—ｐＨ曲线呈平顶峰型、在δ－ＭｎＯ呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子／配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。（２）在碱性条件下的海水介质中，砷酸根与水合氧化物和粘土矿物的Ｅ（％）—ｐＨ曲线都呈Ｖ型，这是因为生成了具有一定结构的液—固界面三元络合物之故。（３）在ＮａＣｌ介质中，Ｃａ加入起促进作用，再次证明液—固界面三元络合物生成机理与Ｖ型曲线的内在关系  相似文献   

沉积物对磷酸盐的吸附与释放   总被引：3，自引：0，他引：3  

陈淑珠  钱红  张经 《中国海洋大学学报(自然科学版)》1997,(3)

本实验研究黄河口水文站沉积物对黄河水磷的吸附释放过程和东海１１１号站位沉积物对海水磷的吸附释放过程。并摸拟黄河沉积物在海水中磷的吸附释放过程。结果表明：底沉积物对磷的吸附相当迅速，无论是河泥还是海泥在２４ｈ内均能达到吸附平衡。吸附量与沉积物的量和水中原有磷的浓度有关，在不同的ｐＨ条件下，沉积物对磷的吸附是有显著差别的  相似文献   

Chemistry of marine resources-ⅩⅨ. The molecule design and synthesis of crow-link type alkyd resin and its enrichment behaviour for potassium ion in sea water     

Sun Yushan  Feng Fei  Sun Hanzhang  Peng Qiqiang  Xia Zongfeng  Wang Wei 《海洋学报(英文版)》1994,13(3):377-388

This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively.  相似文献